Contact Information

Biography

Dr. Michael Van Stipdonk is an Associate Professor in the Department of Chemistry and Biochemistry at Duquesne. He is also the co-director of the Agilent Center of Excellence in Mass Spectrometry.

Dr. Van Stipdonk received a B.A. degree in Chemistry from the University of Detroit. He earned a Ph.D. in chemistry from Texas A&M University. The subject of his dissertation was the emission of secondary ions from solid surfaces following energetic ion impacts, and the use of this emission to determine nano-scale molecular composition. In his post-doctoral research, also at Texas A&M, Dr. Van Stipdonk was a leading figure in the introduction of polyatomic primary ions for surface analysis by secondary ion mass spectrometry.

Dr. Van Stipdonk began his academic career at Wichita State University, where his research areas included studies of peptide fragmentation mechanisms using tandem mass spectrometry and general trends (thermodynamic and kinetic) in gas-phase ion chemistry. This research continues at Duquesne, where his group is advancing the use of tandem mass spectrometry and ion spectroscopy to determine reactant and product ion composition and structure.

Dr. Van Stipdonk awards and honors include a National Science Foundation CAREER grant and the Kansas Biomedical Infrastructure Faculty-Scholar Award. He is a member of the editorial board of the Journal of the American Society for Mass Spectrometry (ASMS). As a member of the ASMS he has served as coordinator for the surface science, metal ions, and peptide fragmentation interest groups and chaired numerous technical sessions at the society’s annual meeting. He is also a member of the American Chemical Society.

Education

  • BA Chemistry, University of Detroit
  • PhD Chemistry, Texas A&M University

Research Interests

  • Mass Spectrometry
  • Ion Spectroscopy
  • Analytical and Physical Chemistry

School

About

  1. "Formation of a Formal U6+ Chelate through Double Gas-phase Activation of Uranyl with a Catecholamide Organic Ligand" Abergel, R. A. J.; de Jong, W. A.; Deblonde, G. J-P. ; Dau, P. D.; Captain, I.; Eaton, T. M.; Jian, J.; van Stipdonk, M. J.; Martens, J.; Berden, G.; Oomens, J.; Gibson, J. submitted to Nature Chemistry, 2017.
  2. "Revealing Disparate Chemistries of Protactinium and Uranium. Synthesis of the Molecular Uranium Tetroxide Anion, UO4-." de Jong, W. A.; Dau, P.; Wilson, R.; Marçalo, J.; Van Stipdonk, M. J.; Corcovilos, T.; Berden, G.; Martens, J.; Oomens, J.; Gibson, J. K. Inorg. Chem. 2017, in press (DOI:10.1021/acs.inorgchem.7b00144).
  3. "Thermodynamics and Reaction Mechanisms of Decomposition of the Simplest Protonated Tripeptide, Triglycine: A Guided Ion Beam and Computational Study". Mookherjee, A.; Van Stipdonk, M. J.; Armentrout, P. B. J. Am. Soc. Mass Spectrom. 2017, in press (DOI: 10.1007/s13361-106-1590-y).
  4. "Synthesis and Hydrolysis of Uranyl, Neptunyl, and Plutonyl Gas-phase Complexes Exhibiting Discrete Actinide-Carbon Bonds". Dau, P. D.; Rios, D.; Gong, Y.; Michelini, M. C.; Marcalo, J.; Shuh, D. K.; Mogannam, M.; Van Stipdonk, M. J.; Corcovilos, T. A.; Martens, J. K.; Berden, G.; Oomens, J.; Redlich, B.; Gibson, J. K. Organometallics 2016, 35, 1228-1240.
  5. "Electronic Structure and Characterization of a Uranyl di-15-crown-5 Complex with an Unprecedented Sandwich Structure". Hu, S.-X.; Gibson, J. K.; Li, W.-L.; Van Stipdonk, M. J.; Martens, J.; Berden, G.; Redlich, B.; Oomens, J.; Li, J. Chem. Comm. 2016, 52, 12761-12764.
  6. "Gas Phase Reactions of Ions Derived from Anionic Uranyl Formate and Uranyl Acetate Complexes". Perez, E.; Hanley, C.; Koehler, S.; Pestok, J.; Polonsky, N.; Van Stipdonk, M. J.; J. Am. Soc. Mass Spectrom. 2016, 27, 1989-1998.
  7. "Collision-induced Dissociation of Uranyl-methoxide and Uranyl-ethoxide Cations: Formation of UO2H+ and Uranyl-alkyl Product Ions". Van Stipdonk, M. J.; Hanley, C.; Perez, E.; Pestok, J.; Mihm, P.; Corcovilos, T. A.; Rapid Comm. Mass Spectrom. 2016, 30, 1879-1890.
  8. "A Mixed Valence Zinc Ditholene System with Spectator Metal and Reactor Ligand". Ratvasky, S. C.; Mogesa, B.; van Stipdonk, M. J.; Basu, P.; Polyhedron, 2016, 26, 2449-2454.
  9. "Dissociation of Gas-Phase, Doubly-Charged Uranyl-Acetone Complexes by Collisional Activation and Infrared Photodissociation". Van Stipdonk, M. J.; O'Malley, C.; Plaviak, A.; Martin, D.; Pestok, J.; Mihm, P. A.; Hanley, C. G.; Corcovilos, T.; Gibson, J. K.; Bythell, B. J.; Int. J. Mass Spectrom. 2016, 396, 22-34.
  10. "Apparent Activation of H2O and Elimination of H2 from Gas-Phase Mixed Metal Complexes Containing Silver, Calcium and Deprotonated Glycine". Osburn, S.; Plaviak, A.; Pestok, J.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2016, 30, 101-111.
  11. "Even-electron (M-H)+ ions generated by loss of AgH from Argentinated peptides with N-terminal imine groups". Plaviak, A.; Osburn, S.; Patterson, K.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2016, 30, 69-80.
  12. "IRMPD spectroscopy reveals a novel rearrangement reaction for modified peptides that involves elimination of the N-terminal amino acid". van Stipdonk, Michael J.; Patterson, Khiry; Gibson, John K.; Berden, Giel; Oomens, Jos.; Int. J. Mass Spectrom. 2015, 379, 165-178.
  13. "Infrared Multiphoton Dissociation Spectroscopy of a Gas-Phase Complex of Uranyl and 3-Oxa-Glutaramide: An Extreme Red-Shift of the [O=U=O]2+ Asymmetric Stretch". Gibson, J. K.; Hu, H.-S.; Van Stipdonk, M. J.; Berden, G.; Oomens, J.; Li, J.; J. Phys. Chem. A 2015, 119, 3366-3374.
  14. "Solution, Solid, and Gas Phase Studies on a Nickel Dithiolene System: Spectator Metal and Reactor Ligand". Mogesa, B.; Perera, E.; Rhoda, H. M.; Gibson, J. K.; Oomens, J.; Berden, G.; van Stipdonk, M. J.; Nemykin, V. N.; Basu, P. Inorg. Chem. 2015, 54, 7703-7716.
  15. "Gas-phase tyrosine-to-cysteine radical migration in model systems". Lesslie, M.; Osburn, S.; van Stipdonk, M. J.; Ryzhov, V. Eur. J. Mass Spectrom. 2015, 21, 589-597.
  16. "Formation of Bare UO22+ and NUO+ By Fragmentation of Gas-Phase Uranyl-Acetonitrile Complexes". Van Stipdonk, M. J.; del Carmen Michelini, M.; Plaviak, A.; Martin, D.; Gibson, J. K.; J. Phys. Chem. A, 2014, 118, 7838-7846.
  17. "Infrared multiple-photon dissociation spectroscopy of deprotonated 6-hydroxynicotinic acid". van Stipdonk, Michael J.; Kullman, Michael J.; Berden, Giel; Oomens, Jos.; Rapid Comm. Mass Spectrom. 2014, 28, 691-698.
  18. "Infrared Multiple Photon Dissociation Spectroscopy of a Gas-Phase Oxo-Molybdenum Complex with 1,2-Dithiolene Ligands". van Stipdonk, M. J.; Basu, P.; Dille, S. A.; Gibson, J. K.; Berden, G.; Oomens, J.; J. Phys. Chem. A 2014, 118, 5407-5418.
  19. "Infrared multiple photon dissociation spectroscopy of Group I and Group II metal complexes with Boc-hydroxylamine". Dain, Ryan P.; Gresham, Gary; Groenewold, Gary S.; Steill, Jeffrey D.; Oomens, Jos; Van Stipdonk, Michael J. Rapid Comm. Mass Spectrom. 2013, 27, 1867-1872.
  20. "Hiding in Plain Sight: Unmasking the Diffuse Spectral Signatures of the Protonated N-Terminus in Isolated Dipeptides Cooled in a Cryogenic Ion Trap". Leavitt, C. M.; DeBlase, A. F.; Johnson, C. J.; van Stipdonk, M.; McCoy, A. B.; Johnson, M. A. J. Phys. Chem. Lett. 2013, 4, 3450-3457.
  21. "Electron transfer dissociation of dipositive uranyl and plutonyl coordination complexes". Rios, D.; Rutkowski, P. X.; Shuh, D. K.; Bray, T. H.; Gibson, J. K.; Van Stipdonk, M. J.; J. Mass Spectrom. 2011, 46, 1247-1254.
  22. "Isomer-Specific IR-IR Double Resonance Spectroscopy of D2-Tagged Protonated Dipeptides Prepared in a Cryogenic Ion Trap". Leavitt, C. M.; Wolk, A. B.; Fournier, J. A.; Kamrath, M. Z.; Garand, E.; Van Stipdonk, M. J.; Johnson, M. A.; J. Phys. Chem. Lett. 2012, 3, 1099-1105.
  23. "IRMPD spectroscopy b2 ions from protonated tripeptides with 4-aminomethyl benzoic acid residues". Kullman, M. J.; Molesworth, S.; Berden, G.; Oomens, J.; Van Stipdonk, M. J.; Int. J. Mass Spectrom. 2012, 316-318, 174-181.
  24. "Roles of Acetone and Diacetone Alcohol in Coordination and Dissociation Reactions of Uranyl Complexes". Rios, D.; Schoendorff, G.; Van Stipdonk, M. J.; Gordon, M. S.; Windus, T. L.; Gibson, J. K.; de Jong, W. A.; Inorg. Chem. 2012, 51, 12768-12775.
  25. "IRMPD and DFT study of the loss of water from protonated 2-hydroxynicotinic acid". Van Stipdonk, M.; Kullman, M.; Berden, G.; Oomens, J.; Int. J. Mass Spectrom. 2012, 330-332, 134-143.
  26. "Vibrational spectra of discrete UO22+ halide complexes in the gas phase". Groenewold, G. S.; van Stipdonk, M. J.; Oomens, J.; de Jong, W. A.; Gresham, G. L.; McIlwain, M. E.; Int. J. Mass Spectrom. 2010, 297, 67-75.
  27. "Structure and Reactivity of the Cysteine Methyl Ester Radical Cation". Osburn, S.; Steill, J. D.; Oomens, J.; O'Hair, R. A. J.; van Stipdonk, M.; Ryzhov, V.; Chem. Eur. J. 2011, 17, 873-879.
  28. "Investigation of Uranyl Nitrate Ion Pairs Complexed with Amide Ligands Using Electrospray Ionization Ion Trap Mass Spectrometry and Density Functional Theory". Gresham, G. L.; Dinescu, A.; Benson, M. T.; Van Stipdonk, M. J.; Groenewold, G. S.; J. Phys. Chem. A 2011, 115, 3497-3508.
  29. "Vibrational Characterization of Simple Peptides Using Cryogenic Infrared Photodissociation of H2-Tagged, Mass-Selected Ions". Kamrath, M. Z.; Garand, E.; Jordan, P. A.; Leavitt, C. M.; Wolk, A. B.; Van Stipdonk, M. J.; Miller, S. J.; Johnson, M. A.; J. Am. Chem. Soc. 2011, 133, 6440-6448.
  30. "Gas-Phase Coordination Complexes of Dipositive Plutonyl, PuO22+: Chemical Diversity Across the Actinyl Series". Rios, Daniel; Rutkowski, Philip X.; Van Stipdonk, Michael J.; Gibson, John K.; Inorg. Chem. 2011, 50, 4781-4790.
  31. "Structure of the [M+H-H2O]+ Ion from Tetraglycine: A Revisit by Means of Density Functional Theory and Isotope Labeling". Verkerk, U. H.; Zhao, J.; Van Stipdonk, M. J.; Bythell, B. J.; Oomens, J. Hopkinson, A. C.; Siu, K. W. M.; J. Phys. Chem. A 2011, 115, 6683-6687.
  32. "Tridentate N2S ligand from 2,2'-dithiodibenzaldehyde and N,N-dimethylethylenediamine: Synthesis, structure, and characterization of a Ni(II) complex with relevance to Ni Superoxide Dismutase". Zimmerman, J. R.; Smucker, B. W.; Dain, R. P.; Van Stipdonk, M. J.; Eichhorn, D. M.; Inorg. Chim. Acta 2011, 373, 54-61.
  33. "Infrared multiple-photon dissociation spectroscopy of group II metal complexes with salicylate". Dain, R. P.; Gresham, G.; Groenewold, G. S.; Steill, J. D.; Oomens, J.; van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2011, 25, 1837-1846.
  34. "On the Formation of "Hypercoordinated" Uranyl Complexes". Schoendorff, George; de Jong, W. A.; Van Stipdonk, M. J.; Gibson, J. K.; Rios, D.; Gordon, M. S.; Windus, T. L.; Inorg, Chem. 2011, 50, 8490-8493.
  35. "Characterizing the intramolecular H-bond and secondary structure in methylated GlyGlyH+ with H2 predissociation spectroscopy". Leavitt, C. M.; Wolk, A. B.; Kamrath, M. Z.; Garand, E.; Van Stipdonk, M. J.; Johnson, M. A.; J. Am. Soc. Mass Spectrom. 2011, 22, 1941-1952.
  36. "Gas-phase coordination complexes of UVIO22+, NpVIO22+, and PuVIO22+ with dimethylformamide". Rutkowski, P. X.; Rios, D.; Gibson, J. K.; Van Stipdonk, M. J.; J. Am. Soc. Mass Spectrom. 2011, 22, 2042-2048.
  37. "The gas-phase bis-uranyl nitrate complex [(UO2)2(NO3)5]-: Infrared spectrum and structure". Groenewold, G. S.; van Stipdonk, M. J.; Oomens, J. de Jong, W. A.; McIlwain, M. E.; Int. J. Mass Spectrom. 2011, 308, 175-180.
  38. "A Study of Fragmentation of Protonated Amides of Some Acylated Amino Acids by Tandem Mass Spectrometry: Observation of an Unusual Nitrilium Ion". Talaty, E. R.; Young, S. M.; Dain, R. P.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2011, 25, 1119-1129.
  39. "Structure of [M+H-H2O]+ from protonated tetraglycine revealed by tandem mass spectrometry and IRMPD spectroscopy". Bythell, Benjamin J.; Dain, Ryan P.; Curtice, Stephanie S.; Oomens, Jos; Steill, Jeffrey D.; Groenewold, Gary S.; Paizs, Bela; Van Stipdonk, Michael J.; J. Phys. Chem. A 2010, 114, 5076-5082.
  40. "Apparent Inhibition by Arginine of Macrocyclic b Ion Formation from Singly Charged Protonated Peptides". Molesworth, S. P.; Van Stipdonk, M. J.; J. Am. Soc. Mass Spectrom. 2010, 21, 1322-1328.
  41. "Influence of Amino Acid Side Chains on Apparent Selective Opening of Cyclic b5 Ions". Molesworth, S.; Osburn, S.; Van Stipdonk, M.; J. Am. Soc. Mass Spectrom. 2010, 21, 1028-1036.
  42. "Variable Denticity in Carboxylate Binding to the Uranyl Coordination Complexes". Groenewold, G. S.; de Jong, W. A.; Oomens, J.; Van Stipdonk, M. J.; J. Am. Soc. Mass Spectrom. 2010, 21, 719-727.
  43. "IRMPD Spectroscopy of Gas-Phase Sodium and Potassium Chlorate Anions". Dain, R. P.; Leavitt, C. M.; Oomens, J.; Steill, J. D.; Groenewold, G. S.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2010, 24, 232-238.
  44. "Influence of Size on Apparent Scrambling of Sequence During CID OF b-Type Ions". Molesworth, S.; Young, S.; Van Stipdonk, M.; J. Am. Soc. Mass Spectrom. 2009, 20, 2174-2181.
  45. "Spectroscopic Evidence for Mobilization of Amide Position Protons During CID of Peptide Ions". Molesworth, S.; Leavitt, C. M.; Groenewold, G. S.; Oomens, J.; Steill, J.; van Stipdonk, M.; J. Am. Soc. Mass Spectrom. 2009, 20, 1841-1845.
  46. "IRMPD Spectroscopy of Potassium-cationized Triethylphosphate". van Stipdonk, M. J.; Leavitt, C. M.; Oomens, J.; Steill, J.; Groenewold, G. S.; Rapid Comm. Mass Spectrom. 2009, 23, 2706-2710.
  47. "Cerium Oxyhydroxide Clusters: Formation, Structure and Reactivity". Aubriet, F.; Gaumet, J.-J.; de Jong, W. A.; Groenewold, G. S.; Gianotto, A. K.; McIlwain, M. E.; Van Stipdonk, M. J.; Leavitt, C. M.; J. Phys. Chem. A, 2009, 113, 6239-6252.
  48. "Infrared Spectroscopy of Fragments of Protonated Peptides: Direct Evidence for Macrocyclic Structures of b5 Ions". Erlekam, U.; Bythell, B. J.; Scuderi, D.; Van Stipdonk, M.; Paizs, B.; Maitre, P.; J. Am. Chem. Soc. 2009, 131, 11503-11508.
  49. "IRMPD Spectroscopy of Anionic Group II Metal Nitrate Clusters". Leavitt, C. M.; Oomens, J.; Dain, R. P.; Steill, J. D.; Groenewold, G. S.; Van Stipdonk, M. J.; J. Am. Soc. Mass Spectrom. 2009, 20, 722-782.
  50. "Addition of H2O and O2 to Acetone and Dimethylsulfoxide Ligated Uranyl(V) Dioxocations". Leavitt, C. M.; Bryantsev, V. S.; de Jong, W. A.; Diallo, M. S.; Goddard III, W. A.; Groenewold, G. S.; Van Stipdonk, M. J.; J. Phys. Chem. A, 2009, 113, 2350-2358.
  51. "Iron and Cobalt Complexes of 2,6-Diacetylpyridine-bis(R-thiosemicarbazone) (R=H, phenyl) Showing Unprecedented Ligand Deviation from Planarity". Panja, A.; Campana, C.; Leavitt, C.; Van Stipdonk, M. J.; Eichhorn, D. M.; Inorg. Chim. Acta, 2009, 362, 1348-1354.
  52. "Spectroscopic Evidence for an Oxazolone Structure of the b2 Fragment Ion from Protonated Tri-alanine". Oomens, J.; Young, S.; Molesworth, S.; van Stipdonk, M.; J. Am. Soc. Mass Spectrom. 2009, 20, 334-339.
  53. "Sequence Scrambling Fragmentation Pathways of Protonated Peptides". Bleiholder, C.; Osburn, S. M.; Williams, T. D.; Suhai, S.; Van Stipdonk, M. J.; Harrison, A.; Paizs, B.; J. Am. Chem. Soc. 2008, 130, 17774-17789.
  54. "Formation of (b3-1+cat)+ Ions from Metal-cationized Tetrapeptides Containing β-alanine, γ-aminobutyric acid or ε-aminocaproic Acid Residues". Osburn, S. M.; Ochola, S. O.; Talaty, E. R.; Van Stipdonk, M. J.; J. Mass Spectrom. 2008, 43, 1458-1469.
  55. "Computational Investigation of Group I Metal-Chlorate Ion Pairs and Their Monohydrates". Dain, R. P.; Van Stipdonk, M. J.; J. Mol StructureTHEOCHEM, 2008, 868, 42-49.
  56. "2-Electron 3-Atom Bond in Side-on (η2) Superoxo Complexes: U(IV) and U(V) Dioxo Monocations". Bryantsev, V. S.; Cossel, K. C.; Diallo, M. S.; Goddard, III, W. A.; de Jong, W. A.; Groenewold, G. S.; Chien, W.; Van Stipdonk, M. J.; J. Phys. Chem. A, 2008, 112, 5777-5780.
  57. "Generation and Collision-induced Dissociation of Ammonium Tetrafluoroborate Cluster Ions". Dain, R. P.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2008, 22, 2044-2052.
  58. "Spectroscopic Investigation of H Atom Transfer in a Gas-phase Dissociation Reaction: McLafferty Rearrangement of Model Gas-phase Peptide Ions". Van Stipdonk, M. J.; Kerstetter, D. R.; Leavitt, C. M.; Groenewold, G. S.; Steill, J. D.; Oomens, J.; Phys. Chem.-Chem. Phys. 2008, 10, 3209-3221.
  59. "Focus Issue on Peptide Fragmentation". Paizs, B.; Van Stipdonk, M.; J. Am. Soc. Mass Spectrom. 2008, 19, 1717-1718.
  60. "Infrared Multiple-photon Photodissociation of Gas-phase Group II Metal-nitrate Anions". Oomens, J.; Myers, L.; Dain, R. P.; Leavitt, C. M.; Pham, V.; Gresham, G.; Groenewold, G.; Van Stipdonk, M. J.; Int. J. Mass Spectrom. 2008, 273, 24-30.
  61. "Infrared Spectroscopy of Discrete Uranyl Anion Complexes." Groenewold, G. S.; Gianotto, A. K.; McIlwain, M. E.; Van Stipdonk, M. J.; Kullman, M.; Moore, D. T.; Polfer, N. Oomens, J.; Infante, I.; Visscher, L.; Siboulet, B.; de Jong, W. A.; J. Phys. Chem. A 2008, 112, 508-521.
  62. "Infrared spectroscopy of dioxouranium(V) complexes with solvent molecules: effect of reduction". Groenewold, G. S.; Van Stipdonk, M. J.; de Jong, W. A.; Oomens, J.; Gresham, G. L.; McIlwain, M. E.; Gao, D.; Siboulet, B.; Visscher, L.; Kullman, M.; Polfer, N.; ChemPhysChem 2008, 9, 1278-1285.
  63. "Investigation of Acidity and Nucleophilicity of Diphenyldithiophosphinate Ligands Using Theory and Gas-phase Dissociation Reactions". Leavitt, C. M.; Gresham, G. L.; Gaumet, J.-J.; Peterman, D.; Klaehn, J.; Benson, M. T.; Aubriet, F.; Van Stipdonk, M. J.; Groenewold, G. S.; Inorg. Chem. 2008, 47, 3056-3064.
  64. "Vibrational spectroscopy of anionic nitrate complexes of UO22+ and Eu3+ isolated in the gas phase". Groenewold, G. S.; Oomens, J.; de Jong, W. A.; Gresham, G. L.; McIlwain, M. E.; Van Stipdonk, M. J.; Phys. Chem.-Chem. Phys. 2008, 10, 1192-1202.
  65. "Syntheses and crystal structures of 3-tert-butyl-4-cyanopyrazole and its complexes with cobalt(II), manganese(II), and copper(II)". Zhao, N.; Van Stipdonk, M. J.; Eichhorn, D. M.; Polyhedron 2007, 26, 2449-2454.
  66. "Influence of a 4-aminomethylbenzoic acid Residue on Competitive Fragmentation Pathways during CID of Metal Cationized Peptides". Osburn, S.; Ochola, S.; Talaty, E.; Van Stipdonk, M.; Rapid Comm. Mass Spectrom. 2007, 21, 3409-3419.
  67. "Investigation of the Neutral Loss of a Full Amino Acid Mass during CID of b3+ Ion derived from a Model Peptide Containing a 4-aminobutyric Acid Residue". Talaty, E. R.; Chueachavalit, C.; Osburn, S.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2007, 21, 2529-2537.
  68. "Sandwich Compounds of Cyanotrispyrazolylborates: Complexation-Induced Ligand Isomerization". Zhao, N.; Van Stipdonk, .M. J.; Bauer, C.; Campana, C.; Eichhorn, D. M.; Inorg. Chem. 2007, 46, 8662-8667.
  69. "Incorporation of thiolate donation using 2,2'-dithiodibenzaldehyde: Complexes of a pentadentate N2S3 ligand with relevance to the active site of Co nitrile hydratase". Smucker, B. W.; Van Stipdonk, M. J.; Eichhorn, D. M.; J. Inor. Biochem. 2007, 101, 1537-1542.
  70. "Mid-infrared Vibrational Spectra of Gas-phase, Acetone Ligated Cerium Hydroxide Cations". Groenewold, G. S.; Gianotto, A. K.; Cossel, K. C.; Van Stipdonk, M. J.; Oomens, J.; Polfer, N.; Moore, D. T.; de Jong, W. A.; Phys. Chem.-Chem. Phys. 2007, 9, 596-606.
  71. "Collision-induced dissociation of Protonated Tetrapeptides Containing -Alanine, -Aminobutyric Acid, -Aminocaproic Acid or 4-Aminomethylbenzoic Acid Residues". Talaty, E. R.; Cooper, T. J.; Osburn, S. M.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2006, 20, 3443-3455.
  72. "Generation of Gas-phase VO2+, VOOH+ and VO2+-Nitrile Complex Ions by Electrospray Ionization and Collision-induced Dissociation". Parsons, Z.; Leavitt, C.; Duong, T.; Groenewold, G. S.; Gresham, G. L.; Van Stipdonk, M. J.; J. Phys. Chem. A 2006, 110, 11627-11635.
  73. "A Study of the Elimination of Water from Lithium-Cationized Tripeptide Methyl Esters by Means of Tandem Mass Spectrometry and Isotope Labeling". Talaty, E. R.; Cooper, T. J.; Piland, D. L.; Bateman, D. J.; Syed, A.; Stevenson, W.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2006, 20, 3007-3017.
  74. "Transfer of Hydrogen from an -Carbon Position during Formation of a Sequence Ion By Collision-induced Dissociation". Osburn, S.; Van Stipdonk, M. J.; J. Undergrad. Res. Chem. 2006, 3, 105-109.
  75. "Isotope Labeling and Theoretical Study of the Formation of a3 Ions from Protonated Tetraglycine". Cooper, T. J.; Talaty, E.; Grove, J.; Suhai, S.; Paizs, B.; Van Stipdonk, M. J.; J. Am. Soc. Mass Spectrom. 2006, 17, 1654-1664.
  76. "Vibrational Spectroscopy of Mass Selected [UO2(ligand)n]2+ Complexes in the Gas Phase: Comparison with Theory". Groenewold, G. S.; Gianotto, A. K.; Cossel, K. C.; Van Stipdonk, M. J.; Moore, D. T.; Polfer, N.; Oomens, J.; de Jong, W. A.; Visscher, L.; J. Am. Chem. Soc. 2006, 128, 4802-4813.
  77. "Gas-phase Uranyl-Nitrile Complex Ions." Van Stipdonk, M. J.; Chien, W.; Bulleigh, K.; Wu, Q.; Groenewold, G. S.; J. Phys. Chem. A, 2006, 110, 959-970.
  78. "Binding of Molecular O2 to Di- and Tri-Ligated [UO2]+". Groenewold, G. S.; Cossel, K. C.; Gresham, G. L.; Gianotto, A. K.; Appelhans, A. D.; Olson, J. E.; Van Stipdonk, M. J.; Chien, W.; J. Am. Chem. Soc. 2006, 128, 3075-3084.
  79. "Investigation of Intra-molecular Proton Migration in a Series of Model, Metal-Cationized Tripeptides Using In-Situ Generation of an Isotope Label". Bulleigh, K.; Howard, A.; Do, T.; Wu, Q.; Anbalagan, V.; Van Stipdonk, M.; Rapid Comm. Mass Spectrom. 2006, 20, 227-232.
  80. "Mechanism-based inactivation of human leukocyte elastase via an enzyme-induced sulfonamide fragmentation process". Wei, L.; Lai, Z.; Gan, X.; Alliston, K. R.; Zhong, J.; Epp, J. B.; Tu, J.; Perera, A. B.; Van Stipdonk, M.; Groutas, W. C.; Arch. Biochem. Biophys. 2004, 429, 60-70.
  81. "Gas-phase Complexes Containing the Uranyl Ion and Acetone". Van Stipdonk, M. J.; Chien, W.; Anbalagan, V.; Bulleigh, K.; Hanna, D.; Groenewold, G. S.; J. Phys. Chem. A, 2004, 108, 10448-10457.
  82. "CID MS/MS of Desferrioxamine Siderophore Complexes from ESI of UO22+, Fe3+ and Ca2+ Solutions". Groenewold, G. S.; Van Stipdonk, M. J.; Gresham, G. L.; Chien, W.; Bulleigh, K.; Howard, A.; J. Mass Spectrom. 2004, 39, 752-761.
  83. "A coordination polymer from a cyanoscorpionate complex". Siemer, C. J.; VanStipdonk, M. J.; Kahol, P. K.; Eichhorn, D. M.; Polyhedron 2004, 23, 235-238.
  84. "Intrinsic Hydration of Uranyl-Hydroxide, -Nitrate and -Acetate Complexes". Chien, W.; Hanna, D.; Anbalagan, V.; Gresham, G.; Groenewold, G.; Zandler, M.; Van Stipdonk, M. J.; J. Am. Soc. Mass Spectrom. 2004, 15, 777-783.
  85. "Influence of "Alternative" C-terminal Amino Acids on the Formation of (b3+17+Cat)+ Products from Metal Cationized Synthetic Tetrapeptides". Anbalagan, V.; Rajagopalachary, S.; Bulleigh, K.; Silva, A. T. M.; Perera, B. A.; Talaty, E. R.; Van Stipdonk, M. J.; J. Mass Spectrom. 2004, 39, 495-510.
  86. "Gas-Phase Hydration of U(IV), U(V), and U(VI) Dioxo Monocations". Gresham, G. L.; Gianotto, A. K.; de B. Harrington, P.; Cao, L.; Scott, J. R.; Olson, J. E.; Appelhans, A. D.; Van Stipdonk, M. J.; Groenewold, G. S.; J. Phys. Chem. A 2003, 107, 8530-8538.
  87. "Gas-phase investigation of Pd(II)-alanine complexes with small native and derivatized peptides containing histidine". Anbalagan, V.; Van Stipdonk, M. J.; J. Mass Spectrom. 2003, 38, 982-989.
  88. "Formation of an ethylene-bridged bis(benzisothiazole) dication by oxidative decomplexation of Ni(tsalen) with FeCl3". Goswami, N.; Van Stipdonk, M. J.; Eichhorn, D. M.; Inorg. Chem. Comm. 2003, 6, 86-89.
  89. "Elucidation of the Collision-induced Dissociation Pathways of Water and Alcohol Coordinated Complexes Containing the Uranyl Cation". Van Stipdonk, M.; Gresham, G.; Groenewold, G.; Anbalagan, V.; Hanna, D.; Chien, W.; J. Am. Soc. Mass Spectrom. 2003, 14, 1205-1214.
  90. "Gas-Phase Hydration and Alcohol Addition Reactions of Complexes Composed of Ag+ and a Single Alcohol Molecule". Hanna, D.; Silva, M.; Morrison, J.; Tekarli, S.; Anbalagan, V.; Van Stipdonk, M.; J. Phys. Chem. A, 2003, 107, 5528-5537.
  91. "McLafferty-type Rearrangement in the Collision Induced Dissociation of Li+, Na+ and Ag+ Cationized Esters of N-acetylated Peptides". Anbalagan, V.; Niyakorn, G.; Patel, J.; Van Stipdonk, M. J.; Rapid Comm. Mass Spectrom. 2003, 17, 291-300.
  1. Faculty Early Career Development (CAREER) Award, National Science Foundation
  2. Faculty-Scholar Award, NIH-Kansas Biomedical Research Infrastructure Network (K-BRIN)
  3. Seaborg Lecturer, Seaborg Center, Lawrence Berkeley National Laboratory